On the left is a Photomicrograph showing the corrosion pit that worked itself to the outside surface of the condenser tube.
Severe
pitting of chillers absorber and condenser Tubes.
occurred in a system utilizing 4" to 6" steel piping with an open
cooling
tower.
It is important to note that badly maintained cooling
tower water circuits in a chiller system can cause very rapid corrosion
of chiller
absorber and condenser tubing. In fact, it is
not uncommon
that even in new installations, such corrosion
could
completely destroy a chiller in one to three
years. One very
common scenario is as follows:
Algae, spores, sand and other debris builds up
to cause
fouling of the absorber and condenser tubes.
As the fouling
progresses, localized, differential corrosion
cells begin to
form. The differential corrosion cells cause
pitting corrosion
and attack the internal areas of the absorber
and condenser
tubes.
As the pitting corrosion progresses, it causes
wastage of
copper material. Copper then plates out on the
interior
surfaces of the steel piping material. A
combination of low pH
values (6-7) along with the warm condenser
water and the
copper plating out on the steel causes
corrosion to then
progress to the steel piping. This corrosion
process develops
tubercle material which, due to the water
velocity, periodically
breaks off and ends up in the cooling tower
water circuit.
The iron oxide that then enters the cooling
tower water circuit
begins to work its way to the absorber and
condenser tubes,
accumulate with the algae, spores, sand, etc.
and begins to
cause increased fouling of the tubes. Once
fouling rapidly
accelerates, cleaning brushes utilized in the
chillers usually
becomes ineffective. Water flows and water
velocities begin to
severely decrease and tends to decrease the
effectiveness of
cleaning brushes which may be installed.
Therefore, don't
depend upon them in this type of situation.
This type of corrosion cycle becomes self
feeding. The more
corrosion, the more you get increased fouling
which then
creates increased corrosion and so on and so
on. To stop the
process, you must start with a complete system
cleaning,
keeping the cooling water clean and making
sure that the
water pH stays in the 8 to 8.5 range or at the
pH level required,
depending on the water treatment chemicals
utilized in the
system.
Labels: absorber corrosion, chiller corrosion, condenser corrosion, copper plating corrosion, Hal Finkelstein, pitting corrosion